10,10′‐Bi(trispiro[2.0.2.0.2.1]decylidene): a Highly Nucleophilic Olefinic Hydrocarbon
Identifieur interne : 001476 ( Main/Exploration ); précédent : 001475; suivant : 00147710,10′‐Bi(trispiro[2.0.2.0.2.1]decylidene): a Highly Nucleophilic Olefinic Hydrocarbon
Auteurs : Wenck [Allemagne] ; de Meijere [Allemagne] ; Gerson [Suisse] ; Gleiter [Allemagne]Source :
- Angewandte Chemie International Edition in English [ 0570-0833 ] ; 1986-04.
Abstract
The title compound 1 is a record olefin in more ways than one. Not only the four α‐but also the two β‐spirocyclopropane groups exert a donor effect on the double bond. The π‐ionization potential of 7.3 eV and the oxidation potential of 0.74 V are the lowest values observed so far for monoolefins without heteroatom donor substituents.
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DOI: 10.1002/anie.198603351
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